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- W2011187957 abstract "Optical absorption line shape due to the transition from the ground state of A 1 g symmetry to the quasi-Jahn-Teller system of accidentally degenerate electronic states of A 1 g and T 1 u symmetry coupled through t 1 u -mode phonon is calculated by three methods, that is, the semi-classical approximation, the independent ordering approximation and the exact method by numerical diagonalization of the vibronic Hamiltonian. In the strong coupling and/or high temperature limit, the line shape is composed of a strong delta function-like central peak and a pair of weak wing part. It is found that the independent ordering approximation does not reproduce the exact line shape for intermediate region so well as in the case of E × e system. The vibronic spectrum for non-degenerate case is also discussed." @default.
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- W2011187957 date "1980-06-01" @default.
- W2011187957 modified "2023-09-27" @default.
- W2011187957 title "Quasi-Jahn-Teller Optical Absorption Line Shape due to Transition from A1g to (A1g + T1u)×t1u System" @default.
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- W2011187957 doi "https://doi.org/10.1143/jpsj.48.1990" @default.
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