Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011190087> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2011190087 endingPage "7756" @default.
- W2011190087 startingPage "7750" @default.
- W2011190087 abstract "Toluene solutions of composition Et(3)ZnLi react rapidly with aldehydes and ketones to form addition products. Et(3)ZnNa and Et(3)ZnK solutions react readily with the same substrates although metalation, as well as addition, is significant with substrates having alpha-hydrogens. The Et(3)ZnM solutions react with 2-cyclohexenone to give mainly the 1,4-addition product. Relative rates of addition of Et(3)ZnLi to substituted acetophenones give a Hammett rho of 2.78. Addition of Et(3)ZnLi to acetophenone is slowed significantly by alpha and ortho methyl substituents; relative rates of addition to acetophenone, o-methylacetophenone, and tert-butyl phenyl ketone are 1.00, 0.012, and 0.003." @default.
- W2011190087 created "2016-06-24" @default.
- W2011190087 creator A5035493418 @default.
- W2011190087 creator A5051704850 @default.
- W2011190087 date "2000-10-25" @default.
- W2011190087 modified "2023-09-24" @default.
- W2011190087 title "Reactions of Et<sub>3</sub>ZnLi with Ketones: Electronic and Steric Effects<sup>1</sup>" @default.
- W2011190087 cites W1976236039 @default.
- W2011190087 cites W1989010608 @default.
- W2011190087 cites W1990051372 @default.
- W2011190087 cites W2007614240 @default.
- W2011190087 cites W2010358471 @default.
- W2011190087 cites W2013396410 @default.
- W2011190087 cites W2014243178 @default.
- W2011190087 cites W2021285083 @default.
- W2011190087 cites W2026417312 @default.
- W2011190087 cites W2038969936 @default.
- W2011190087 cites W2041759178 @default.
- W2011190087 cites W2046629999 @default.
- W2011190087 cites W2054740316 @default.
- W2011190087 cites W2056556155 @default.
- W2011190087 cites W2069607377 @default.
- W2011190087 cites W2070601852 @default.
- W2011190087 cites W2083582911 @default.
- W2011190087 cites W2091947825 @default.
- W2011190087 cites W2096819076 @default.
- W2011190087 cites W2110368092 @default.
- W2011190087 cites W2126982282 @default.
- W2011190087 cites W2158095375 @default.
- W2011190087 cites W2160790360 @default.
- W2011190087 cites W2161329689 @default.
- W2011190087 cites W2162227409 @default.
- W2011190087 cites W2316167812 @default.
- W2011190087 cites W2319057101 @default.
- W2011190087 cites W2611320456 @default.
- W2011190087 cites W2950167936 @default.
- W2011190087 cites W2952939610 @default.
- W2011190087 cites W2953208143 @default.
- W2011190087 cites W2953344507 @default.
- W2011190087 doi "https://doi.org/10.1021/jo000630j" @default.
- W2011190087 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11073576" @default.
- W2011190087 hasPublicationYear "2000" @default.
- W2011190087 type Work @default.
- W2011190087 sameAs 2011190087 @default.
- W2011190087 citedByCount "25" @default.
- W2011190087 countsByYear W20111900872013 @default.
- W2011190087 countsByYear W20111900872018 @default.
- W2011190087 countsByYear W20111900872020 @default.
- W2011190087 crossrefType "journal-article" @default.
- W2011190087 hasAuthorship W2011190087A5035493418 @default.
- W2011190087 hasAuthorship W2011190087A5051704850 @default.
- W2011190087 hasConcept C155647269 @default.
- W2011190087 hasConcept C161790260 @default.
- W2011190087 hasConcept C178790620 @default.
- W2011190087 hasConcept C185592680 @default.
- W2011190087 hasConcept C201194858 @default.
- W2011190087 hasConcept C2775855785 @default.
- W2011190087 hasConcept C2775888733 @default.
- W2011190087 hasConcept C2777386583 @default.
- W2011190087 hasConcept C2777738585 @default.
- W2011190087 hasConcept C2778142098 @default.
- W2011190087 hasConcept C2780450521 @default.
- W2011190087 hasConceptScore W2011190087C155647269 @default.
- W2011190087 hasConceptScore W2011190087C161790260 @default.
- W2011190087 hasConceptScore W2011190087C178790620 @default.
- W2011190087 hasConceptScore W2011190087C185592680 @default.
- W2011190087 hasConceptScore W2011190087C201194858 @default.
- W2011190087 hasConceptScore W2011190087C2775855785 @default.
- W2011190087 hasConceptScore W2011190087C2775888733 @default.
- W2011190087 hasConceptScore W2011190087C2777386583 @default.
- W2011190087 hasConceptScore W2011190087C2777738585 @default.
- W2011190087 hasConceptScore W2011190087C2778142098 @default.
- W2011190087 hasConceptScore W2011190087C2780450521 @default.
- W2011190087 hasIssue "23" @default.
- W2011190087 hasLocation W20111900871 @default.
- W2011190087 hasLocation W20111900872 @default.
- W2011190087 hasOpenAccess W2011190087 @default.
- W2011190087 hasPrimaryLocation W20111900871 @default.
- W2011190087 hasRelatedWork W1536086220 @default.
- W2011190087 hasRelatedWork W1553995818 @default.
- W2011190087 hasRelatedWork W1963756558 @default.
- W2011190087 hasRelatedWork W2011190087 @default.
- W2011190087 hasRelatedWork W2024024431 @default.
- W2011190087 hasRelatedWork W2033691279 @default.
- W2011190087 hasRelatedWork W2091529667 @default.
- W2011190087 hasRelatedWork W4252880569 @default.
- W2011190087 hasRelatedWork W4383682564 @default.
- W2011190087 hasRelatedWork W2466772677 @default.
- W2011190087 hasVolume "65" @default.
- W2011190087 isParatext "false" @default.
- W2011190087 isRetracted "false" @default.
- W2011190087 magId "2011190087" @default.
- W2011190087 workType "article" @default.