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- W2011191755 abstract "In general, palladium-carbon (Pd/C) catalyzed hydrogenation of epoxides affords the corresponding primary and secondary alcohols as a mixture. It has been found that the catalytic activity of a Pd/C-ethylenediamine complex catalyst [Pd/C(en)] in the hydrogenolysis of epoxide functions is drastically reduced. Herein we describe a mild and chemoselective method for the hydrogenation of olefin, nitro, and azide functions with retention of the epoxide function. The chemoselectivity was accomplished by using a combination of 5 % Pd/C(en) and THF as solvent. A significant drop in the chemoselectivity of the hydrogenation is observed with 5 % Pd/C(en) in MeOH. These results reinforce the utility of epoxides as important precursors of alcohols in synthetic chemistry." @default.
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- W2011191755 date "2000-06-16" @default.
- W2011191755 modified "2023-10-11" @default.
- W2011191755 title "Highly Chemoselective Hydrogenation with Retention of the Epoxide Function Using a Heterogeneous Pd/C-Ethylenediamine Catalyst and THF" @default.
- W2011191755 doi "https://doi.org/10.1002/1521-3765(20000616)6:12<2200::aid-chem2200>3.0.co;2-3" @default.
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