FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011197083> ?p ?o ?g. }

• W2011197083 endingPage "88" @default.
• W2011197083 startingPage "75" @default.
• W2011197083 abstract "The C3 alcohols 1-propanol, 2-propanol and prop-2-en-1-ol (allyl alcohol) are catalytically oxidized in He/oxygen to the corresponding carbonyl compounds propanal, acetone and acrolein with high selectivities and yields over Mn3O4. The reaction occurs in the temperature range 400–550 K and yields far over 85% are obtained in the synthesis of acrolein and acetone. The reaction rate is faster for the secondary alcohol 2-propanol, than for the primary ones. The oxidation of the unsaturated allyl alcohol is faster than for the saturated one, 1-propanol. Selectivity is limited by overoxidation of the carbonyl compounds. IR studies show that the high yields obtained in carbonyl compounds production over this catalyst are mainly due to their very weak adsorption. The main factor limiting the selectivity to acetone and, mainly, propanal is their tendency to give enolate anions that further convert into acetaldehyde in both cases. Overoxidation of aldehydes to the corresponding car☐ylate species is a less efficient mechanism limiting selectivity. The selectivity/activity behavior is definitely different than that observed for stoichiometric alcohols oxidations with Mn(III) compounds and also than that observed on other catalysts. This difference is associated to the low surface acidity of the Mn3O4 catalyst." @default.
• W2011197083 created "2016-06-24" @default.
• W2011197083 creator A5006978252 @default.
• W2011197083 creator A5020009712 @default.
• W2011197083 creator A5062097243 @default.
• W2011197083 creator A5063374600 @default.
• W2011197083 creator A5086304725 @default.
• W2011197083 date "1998-01-01" @default.
• W2011197083 modified "2023-09-26" @default.
• W2011197083 title "An FT-IR and flow reactor study of the selective catalytic oxy-dehydrogenation of C3 alcohols on Mn3O4" @default.
• W2011197083 cites W1964122825 @default.
• W2011197083 cites W1977494936 @default.
• W2011197083 cites W1978301002 @default.
• W2011197083 cites W1980598275 @default.
• W2011197083 cites W1981017446 @default.
• W2011197083 cites W1985266455 @default.
• W2011197083 cites W1990015942 @default.
• W2011197083 cites W2007878701 @default.
• W2011197083 cites W2008488050 @default.
• W2011197083 cites W2013349576 @default.
• W2011197083 cites W2016469623 @default.
• W2011197083 cites W2020262913 @default.
• W2011197083 cites W2037603897 @default.
• W2011197083 cites W2051087626 @default.
• W2011197083 cites W2074503801 @default.
• W2011197083 cites W2086802563 @default.
• W2011197083 cites W2089381280 @default.
• W2011197083 cites W2094237503 @default.
• W2011197083 cites W2145884287 @default.
• W2011197083 cites W2152092186 @default.
• W2011197083 cites W4256125526 @default.
• W2011197083 doi "https://doi.org/10.1016/s0926-860x(97)00242-1" @default.
• W2011197083 hasPublicationYear "1998" @default.
• W2011197083 type Work @default.
• W2011197083 sameAs 2011197083 @default.
• W2011197083 citedByCount "45" @default.
• W2011197083 countsByYear W20111970832012 @default.
• W2011197083 countsByYear W20111970832013 @default.
• W2011197083 countsByYear W20111970832014 @default.
• W2011197083 countsByYear W20111970832017 @default.
• W2011197083 countsByYear W20111970832018 @default.
• W2011197083 countsByYear W20111970832019 @default.
• W2011197083 countsByYear W20111970832020 @default.
• W2011197083 crossrefType "journal-article" @default.
• W2011197083 hasAuthorship W2011197083A5006978252 @default.
• W2011197083 hasAuthorship W2011197083A5020009712 @default.
• W2011197083 hasAuthorship W2011197083A5062097243 @default.
• W2011197083 hasAuthorship W2011197083A5063374600 @default.
• W2011197083 hasAuthorship W2011197083A5086304725 @default.
• W2011197083 hasConcept C114157696 @default.
• W2011197083 hasConcept C118792377 @default.
• W2011197083 hasConcept C119889771 @default.
• W2011197083 hasConcept C144082473 @default.
• W2011197083 hasConcept C161790260 @default.
• W2011197083 hasConcept C178790620 @default.
• W2011197083 hasConcept C185592680 @default.
• W2011197083 hasConcept C2777595113 @default.
• W2011197083 hasConcept C2778292535 @default.
• W2011197083 hasConcept C2779607525 @default.
• W2011197083 hasConcept C2779672685 @default.
• W2011197083 hasConcept C2780161600 @default.
• W2011197083 hasConcept C2780422782 @default.
• W2011197083 hasConcept C2781066024 @default.
• W2011197083 hasConcept C2781213060 @default.
• W2011197083 hasConcept C75473681 @default.
• W2011197083 hasConceptScore W2011197083C114157696 @default.
• W2011197083 hasConceptScore W2011197083C118792377 @default.
• W2011197083 hasConceptScore W2011197083C119889771 @default.
• W2011197083 hasConceptScore W2011197083C144082473 @default.
• W2011197083 hasConceptScore W2011197083C161790260 @default.
• W2011197083 hasConceptScore W2011197083C178790620 @default.
• W2011197083 hasConceptScore W2011197083C185592680 @default.
• W2011197083 hasConceptScore W2011197083C2777595113 @default.
• W2011197083 hasConceptScore W2011197083C2778292535 @default.
• W2011197083 hasConceptScore W2011197083C2779607525 @default.
• W2011197083 hasConceptScore W2011197083C2779672685 @default.
• W2011197083 hasConceptScore W2011197083C2780161600 @default.
• W2011197083 hasConceptScore W2011197083C2780422782 @default.
• W2011197083 hasConceptScore W2011197083C2781066024 @default.
• W2011197083 hasConceptScore W2011197083C2781213060 @default.
• W2011197083 hasConceptScore W2011197083C75473681 @default.
• W2011197083 hasIssue "1" @default.
• W2011197083 hasLocation W20111970831 @default.
• W2011197083 hasOpenAccess W2011197083 @default.
• W2011197083 hasPrimaryLocation W20111970831 @default.
• W2011197083 hasRelatedWork W1966480903 @default.
• W2011197083 hasRelatedWork W1968867831 @default.
• W2011197083 hasRelatedWork W2011197083 @default.
• W2011197083 hasRelatedWork W2018730910 @default.
• W2011197083 hasRelatedWork W2027995278 @default.
• W2011197083 hasRelatedWork W2082627234 @default.
• W2011197083 hasRelatedWork W2092560940 @default.
• W2011197083 hasRelatedWork W2362834856 @default.
• W2011197083 hasRelatedWork W2364149130 @default.
• W2011197083 hasRelatedWork W2950842791 @default.
• W2011197083 hasVolume "166" @default.
• W2011197083 isParatext "false" @default.
• W2011197083 isRetracted "false" @default.

• next