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- W2011198260 abstract "The reaction of heptamolybdate, Mo7O246-, with excess hydroxide ion proceeds through base-independent, and base-dependent, pathways. The reaction is strongly dependent upon the salt chosen to maintain constant ionic strength. The values of the base-independent rate constant increase in the order K+(2.5 s-1 at 2.0 mol l-1 KCl and 25.0�C) < Na+ (9 s-1) < Li+ (20 s-1) and those of the base-dependent rate constant in the order K+ (8200 1. mol-1 s-1) < Na+ (10300 1. mol-1 s-1) < Li+ (19600 1. mol-1 s-1). Extensive measurements in mixed cation media show that the effect of ion pairing decreases in the order K+ > Na+ > Li+. The kinetic behaviour and activation parameters are contrasted with those for the base decomposition of decavanadate, V10O286-, and different mechanisms are proposed." @default.
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- W2011198260 date "1975-01-01" @default.
- W2011198260 modified "2023-09-26" @default.
- W2011198260 title "Base decomposition of heptamolybdate" @default.
- W2011198260 doi "https://doi.org/10.1071/ch9752365" @default.
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