FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011203612> ?p ?o ?g. }

• W2011203612 endingPage "2287" @default.
• W2011203612 startingPage "2279" @default.
• W2011203612 abstract "A combination of the “pickup” technique and a double focusing, high-resolution mass spectrometer have been used to generate and study the chemistry of cluster ions of the form Mg+(CH3OH)n and [Mg(CH3OH)n]2+, for n in the range 1−20. The singly charged ions exhibit a switch in intensity between Mg+(CH3OH)n and Mg+OCH3(CH3OH)n-1 at n = 3, which is attributed to an increase in stability of the polarized ion [Mg2+−OCH3-] as more methanol molecules are added to the complex. No doubly charged ions are observed for n =1, and the mass spectrum is dominated by parent ions rather than fragments when n ≥ 2. For each of the two types of ion, the principal unimolecular (metastable) decay channel is the loss of methanol. With the introduction of a collision gas, a very wide range of reaction products is observed for the smaller singly charged ions, with the main fragments being Mg+OCH3, Mg+OH, and Mg+H, which are formed, in some cases, in the presence of additional methanol molecules. Collisional fragmentation of the doubly charged ions is most often accompanied by Coulomb explosion in which charge separation follows the breaking of covalent bonds. However, in some instances the measured kinetic energy releases for the latter process are very much lower than expected, and it is suggested that excess energy is being carried away by very light fragments, e.g., H and H2. Some of the reactions observed for [Mg(CH3OH)n]2+ ions can be accounted for by assuming a range of anion transfer processes." @default.
• W2011203612 created "2016-06-24" @default.
• W2011203612 creator A5024592893 @default.
• W2011203612 creator A5028528461 @default.
• W2011203612 creator A5043508907 @default.
• W2011203612 date "1997-03-01" @default.
• W2011203612 modified "2023-10-10" @default.
• W2011203612 title "Chemistry of Mg⁺ and Mg²⁺ in Association with Methanol Clusters" @default.
• W2011203612 cites W1526397678 @default.
• W2011203612 cites W1964152392 @default.
• W2011203612 cites W1974821647 @default.
• W2011203612 cites W1978884027 @default.
• W2011203612 cites W1985564840 @default.
• W2011203612 cites W1991477391 @default.
• W2011203612 cites W1991724369 @default.
• W2011203612 cites W1991769568 @default.
• W2011203612 cites W1992210899 @default.
• W2011203612 cites W1993449809 @default.
• W2011203612 cites W2012187468 @default.
• W2011203612 cites W2026285661 @default.
• W2011203612 cites W2032468603 @default.
• W2011203612 cites W2035736851 @default.
• W2011203612 cites W2036104798 @default.
• W2011203612 cites W2038011875 @default.
• W2011203612 cites W2065748711 @default.
• W2011203612 cites W2069285430 @default.
• W2011203612 cites W2069417174 @default.
• W2011203612 cites W2070817647 @default.
• W2011203612 cites W2079277621 @default.
• W2011203612 cites W2081868274 @default.
• W2011203612 cites W2082383292 @default.
• W2011203612 cites W2087361743 @default.
• W2011203612 cites W2087546770 @default.
• W2011203612 cites W2089463774 @default.
• W2011203612 cites W2092857847 @default.
• W2011203612 cites W2093826040 @default.
• W2011203612 cites W2094212914 @default.
• W2011203612 cites W2094348323 @default.
• W2011203612 cites W2095275895 @default.
• W2011203612 cites W2096677335 @default.
• W2011203612 cites W2342510659 @default.
• W2011203612 cites W2461511608 @default.
• W2011203612 cites W2990312195 @default.
• W2011203612 cites W3005202792 @default.
• W2011203612 cites W36338746 @default.
• W2011203612 doi "https://doi.org/10.1021/jp9639410" @default.
• W2011203612 hasPublicationYear "1997" @default.
• W2011203612 type Work @default.
• W2011203612 sameAs 2011203612 @default.
• W2011203612 citedByCount "88" @default.
• W2011203612 countsByYear W20112036122012 @default.
• W2011203612 countsByYear W20112036122013 @default.
• W2011203612 countsByYear W20112036122014 @default.
• W2011203612 countsByYear W20112036122015 @default.
• W2011203612 countsByYear W20112036122019 @default.
• W2011203612 countsByYear W20112036122022 @default.
• W2011203612 crossrefType "journal-article" @default.
• W2011203612 hasAuthorship W2011203612A5024592893 @default.
• W2011203612 hasAuthorship W2011203612A5028528461 @default.
• W2011203612 hasAuthorship W2011203612A5043508907 @default.
• W2011203612 hasConcept C102931765 @default.
• W2011203612 hasConcept C111919701 @default.
• W2011203612 hasConcept C113196181 @default.
• W2011203612 hasConcept C121332964 @default.
• W2011203612 hasConcept C135889238 @default.
• W2011203612 hasConcept C145148216 @default.
• W2011203612 hasConcept C147789679 @default.
• W2011203612 hasConcept C162356407 @default.
• W2011203612 hasConcept C178790620 @default.
• W2011203612 hasConcept C185592680 @default.
• W2011203612 hasConcept C191015642 @default.
• W2011203612 hasConcept C198291218 @default.
• W2011203612 hasConcept C2779607525 @default.
• W2011203612 hasConcept C32909587 @default.
• W2011203612 hasConcept C40325409 @default.
• W2011203612 hasConcept C41008148 @default.
• W2011203612 hasConcept C43617362 @default.
• W2011203612 hasConcept C62520636 @default.
• W2011203612 hasConcept C69402668 @default.
• W2011203612 hasConcept C89464430 @default.
• W2011203612 hasConceptScore W2011203612C102931765 @default.
• W2011203612 hasConceptScore W2011203612C111919701 @default.
• W2011203612 hasConceptScore W2011203612C113196181 @default.
• W2011203612 hasConceptScore W2011203612C121332964 @default.
• W2011203612 hasConceptScore W2011203612C135889238 @default.
• W2011203612 hasConceptScore W2011203612C145148216 @default.
• W2011203612 hasConceptScore W2011203612C147789679 @default.
• W2011203612 hasConceptScore W2011203612C162356407 @default.
• W2011203612 hasConceptScore W2011203612C178790620 @default.
• W2011203612 hasConceptScore W2011203612C185592680 @default.
• W2011203612 hasConceptScore W2011203612C191015642 @default.
• W2011203612 hasConceptScore W2011203612C198291218 @default.
• W2011203612 hasConceptScore W2011203612C2779607525 @default.
• W2011203612 hasConceptScore W2011203612C32909587 @default.
• W2011203612 hasConceptScore W2011203612C40325409 @default.
• W2011203612 hasConceptScore W2011203612C41008148 @default.
• W2011203612 hasConceptScore W2011203612C43617362 @default.
• W2011203612 hasConceptScore W2011203612C62520636 @default.

• next