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• W2011204727 abstract "Photosensitized reactions of molecular oxygen have found far-reaching applications in various fields, and the development of new photosensitizer compounds is of crucial importance. We here describe a new class of triply linked bay-fused diperylene bisimides (DiPBIs) which exhibited several unique features, rendering them a new structural platform for the development of highly efficient and photostable photosensitizers. (i) The extended π-conjugation shifts its absorption into the body’s therapeutic window. (ii) The nonplanarity of the distorted cores enhances the spin−orbit coupled intersystem crossing. (iii) The long-lasting high-energy T1 state facilitates singlet oxygen generation via energy-transfer reaction between T1 and ground-state oxygen." @default.
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• W2011204727 date "2010-08-06" @default.
• W2011204727 modified "2023-10-18" @default.
• W2011204727 title "Exceptional Intersystem Crossing in Di(perylene bisimide)s: A Structural Platform toward Photosensitizers for Singlet Oxygen Generation" @default.
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• W2011204727 doi "https://doi.org/10.1021/jz1008328" @default.
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