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• W2011223581 abstract "The reaction of the oxidovanadium(V) complexes with N,N-dimethylhydrazine was demonstrated to afford the corresponding vanadium(V) dimethylhydrazido complexes. The substituent at the 3-position of the tris(2-hydroxyphenyl)amine ligand was found to influence the electronic environment of the vanadium center. The crystal structure of the non-substituted vanadium(V) dimethylhydrazido complex exhibited a distorted trigonal bipyramidal geometry with phenolate oxygen atoms in equatorial positions and the near-linear V(1)-N(2)-N(3) angle. The vanadium(V) diphenylhydrazido complexes could be obtained by the reaction of the oxidovanadium(V) complexes with N,N-diphenylhydrazine. A distorted trigonal bipyramidal geometry with phenolate oxygen atoms in equatorial positions was also observed in the crystal structure of the non-substituted vanadium(V) diphenylhydrazido complex." @default.
• W2011223581 created "2016-06-24" @default.
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• W2011223581 date "2013-01-01" @default.
• W2011223581 modified "2023-09-28" @default.
• W2011223581 title "Synthesis of vanadium(v) hydrazido complexes with tris(2-hydroxyphenyl)amine ligands" @default.
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• W2011223581 doi "https://doi.org/10.1039/c3dt50533b" @default.
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