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- W2011262570 abstract "The stability constants for nitrato complexes of plutonium(IV) have been determined by solvent extraction method using tri-n-butyl phosphate (TBP) as solvent. It has been shown that following Fomin and Maiorova method, the values of stability constants are higher as compared to the ones obtained by other methods. The method of calculation has been modified so as to minimize the effect of other complexes which are formed by TBP in presence of aqueous nitrate solutions. The values, thus obtained, agree fairly well with the published ones, although the activity coefficients for HNO3. TBP have not been taken into account which are likely to give better results. The stability constants for sulphate ions with plutonium(IV) have also been determined in nitrate media. The values obtained at various nitrate and hydrogen ion concentrations for sulphato complexes agree fairly well showing that the mixed species are present in very small amounts and are neglected in the method of calculation." @default.
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- W2011262570 date "1964-06-01" @default.
- W2011262570 modified "2023-09-25" @default.
- W2011262570 title "Stability constants of nitrate and sulphate complexes of plutonium(IV)" @default.
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- W2011262570 doi "https://doi.org/10.1016/0022-1902(64)80262-1" @default.
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