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- W2011276472 abstract "When 4-nitropyridine N-oxide was allowed to react with p-nitrobenzenesulfenyl chloride, 4-pyridyl 4′-chloropyridinium chloride (V) and 4-(4′-pyridol)pyridine (IV) were obtained, along with p, p-dinitrodiphenyl disulfide, p-nitrobenzenesulfonic acid, and a salt, presumed to have a VI structure. Similar products were formed in the reaction between 4-chloropyridine N-oxide with p-nitrobenzenesulfenyl chloride. In the case of 4-methoxypyridine N-oxide, however, a simple reduction was the main reaction; thus 4-methoxypyridine was obtained, while the other products were the same. As in the case of pyridine- and α-picoline N-oxide, no ring-substituted product was isolated in the reactions of these N-oxides. Apparently, the reaction of these N-oxides with p-nitrobenzenesulfenyl chloride involves the initial formation of the salt, which has a N-sulfenoxy bond, (Remark: Graphics omitted.), which presumably cleaves homolytically in the succeeding step to give the final products." @default.
- W2011276472 created "2016-06-24" @default.
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- W2011276472 date "1967-06-01" @default.
- W2011276472 modified "2023-09-23" @default.
- W2011276472 title "Rearrangements of Tertiary Amine Oxide. XVIII. The Reaction of 4-Substituted Pyridine<i>N</i>-Oxides with<i>p</i>-Nitrobenzenesulfenyl Chloride and<i>p</i>-Nitrobenzenesulfinyl Chloride" @default.
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- W2011276472 doi "https://doi.org/10.1246/bcsj.40.1420" @default.
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