Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011284511> ?p ?o ?g. }
Showing items 1 to 98 of
98
with 100 items per page.
- W2011284511 endingPage "226" @default.
- W2011284511 startingPage "215" @default.
- W2011284511 abstract "Cobalt stabilized carbenes are readily synthesized by reaction of organolithium compounds with (CO)4CoGePh3. The neutral carbenes are formed from the anion thus obtained by treatment with an ethylating reagent. Anions α to the carbene atom can be generated by treatment with a strong base (NaH, RLi) and trapped with Et3OBF4. However attempts to trap both types of anions with chlorosilanes failed, and instead the compound (CO)4CoGePh3 was recovered in good yield. An X-ray structural determination of one of these complexes, (Ph3Ge)(CO)3Co(OEt)Et, shows unusually short bond lengths in the carbene moiety and the linkage trans to the triphenylgermyl group. The unusual chemical behaviour can be related to special features of the structure of the complex." @default.
- W2011284511 created "2016-06-24" @default.
- W2011284511 creator A5012288046 @default.
- W2011284511 creator A5041273864 @default.
- W2011284511 creator A5049302398 @default.
- W2011284511 creator A5070991705 @default.
- W2011284511 creator A5077396691 @default.
- W2011284511 creator A5078163332 @default.
- W2011284511 creator A5086822968 @default.
- W2011284511 date "1979-10-01" @default.
- W2011284511 modified "2023-10-12" @default.
- W2011284511 title "Synthesis, chemical behaviour and crystal structure of cobalt-stabilized carbenes, (Ph3Ge)(CO)3CoC(OEt)R" @default.
- W2011284511 cites W1556952675 @default.
- W2011284511 cites W1963616045 @default.
- W2011284511 cites W1974339290 @default.
- W2011284511 cites W1985915957 @default.
- W2011284511 cites W1990605839 @default.
- W2011284511 cites W2010015344 @default.
- W2011284511 cites W2026049439 @default.
- W2011284511 cites W2035126991 @default.
- W2011284511 cites W2035889328 @default.
- W2011284511 cites W2043068345 @default.
- W2011284511 cites W2051420411 @default.
- W2011284511 cites W2073430106 @default.
- W2011284511 cites W2093481552 @default.
- W2011284511 cites W2145573196 @default.
- W2011284511 cites W2161560228 @default.
- W2011284511 cites W2169721093 @default.
- W2011284511 cites W2314421348 @default.
- W2011284511 cites W2951291957 @default.
- W2011284511 cites W3137497664 @default.
- W2011284511 cites W3137574607 @default.
- W2011284511 doi "https://doi.org/10.1016/s0022-328x(00)95224-0" @default.
- W2011284511 hasPublicationYear "1979" @default.
- W2011284511 type Work @default.
- W2011284511 sameAs 2011284511 @default.
- W2011284511 citedByCount "38" @default.
- W2011284511 countsByYear W20112845112016 @default.
- W2011284511 countsByYear W20112845112018 @default.
- W2011284511 countsByYear W20112845112019 @default.
- W2011284511 countsByYear W20112845112022 @default.
- W2011284511 crossrefType "journal-article" @default.
- W2011284511 hasAuthorship W2011284511A5012288046 @default.
- W2011284511 hasAuthorship W2011284511A5041273864 @default.
- W2011284511 hasAuthorship W2011284511A5049302398 @default.
- W2011284511 hasAuthorship W2011284511A5070991705 @default.
- W2011284511 hasAuthorship W2011284511A5077396691 @default.
- W2011284511 hasAuthorship W2011284511A5078163332 @default.
- W2011284511 hasAuthorship W2011284511A5086822968 @default.
- W2011284511 hasConcept C115624301 @default.
- W2011284511 hasConcept C134121241 @default.
- W2011284511 hasConcept C155647269 @default.
- W2011284511 hasConcept C161790260 @default.
- W2011284511 hasConcept C178790620 @default.
- W2011284511 hasConcept C185592680 @default.
- W2011284511 hasConcept C191897082 @default.
- W2011284511 hasConcept C192562407 @default.
- W2011284511 hasConcept C2776568683 @default.
- W2011284511 hasConcept C2777164566 @default.
- W2011284511 hasConcept C40875361 @default.
- W2011284511 hasConcept C515602321 @default.
- W2011284511 hasConcept C71240020 @default.
- W2011284511 hasConcept C8010536 @default.
- W2011284511 hasConceptScore W2011284511C115624301 @default.
- W2011284511 hasConceptScore W2011284511C134121241 @default.
- W2011284511 hasConceptScore W2011284511C155647269 @default.
- W2011284511 hasConceptScore W2011284511C161790260 @default.
- W2011284511 hasConceptScore W2011284511C178790620 @default.
- W2011284511 hasConceptScore W2011284511C185592680 @default.
- W2011284511 hasConceptScore W2011284511C191897082 @default.
- W2011284511 hasConceptScore W2011284511C192562407 @default.
- W2011284511 hasConceptScore W2011284511C2776568683 @default.
- W2011284511 hasConceptScore W2011284511C2777164566 @default.
- W2011284511 hasConceptScore W2011284511C40875361 @default.
- W2011284511 hasConceptScore W2011284511C515602321 @default.
- W2011284511 hasConceptScore W2011284511C71240020 @default.
- W2011284511 hasConceptScore W2011284511C8010536 @default.
- W2011284511 hasIssue "2" @default.
- W2011284511 hasLocation W20112845111 @default.
- W2011284511 hasOpenAccess W2011284511 @default.
- W2011284511 hasPrimaryLocation W20112845111 @default.
- W2011284511 hasRelatedWork W2045060966 @default.
- W2011284511 hasRelatedWork W2097014657 @default.
- W2011284511 hasRelatedWork W2949184651 @default.
- W2011284511 hasRelatedWork W2949366517 @default.
- W2011284511 hasRelatedWork W2950893765 @default.
- W2011284511 hasRelatedWork W2951269336 @default.
- W2011284511 hasRelatedWork W2951655361 @default.
- W2011284511 hasRelatedWork W2952256733 @default.
- W2011284511 hasRelatedWork W2952556931 @default.
- W2011284511 hasRelatedWork W2953317625 @default.
- W2011284511 hasVolume "179" @default.
- W2011284511 isParatext "false" @default.
- W2011284511 isRetracted "false" @default.
- W2011284511 magId "2011284511" @default.
- W2011284511 workType "article" @default.