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- W2011292013 abstract "Spectral and molecular model computations on homo-dinuclear complexes [M(2)L(2)(H(2)O)(2)Cl(2)] [L=1-(salicylaldeneamino)-3-hydroxypropane, M=Cr(3+), Mn(3+), Fe(3+), Co(3+), Ni(3+) or Cu(3+)] are consistent with a distorted hexa-coordinate geometry. X-band EPR spectral data indicated a rhombic distortion around Cu(II) ion. Magnetic moment and (57)Fe Mössbauer data confirmed a high-spin state electronic configuration (t(2g)(3)e(g)(2), S=5/2) and asymmetric ligand environment around Fe(III) with nuclear transitions Fe(+/-3/2-->1/2) exhibiting Kramer's double degeneracy. The neighboring Fe(III) nuclei in the homo-dinuclear species are antiferromagnetically coupled." @default.
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- W2011292013 date "2010-02-01" @default.
- W2011292013 modified "2023-09-30" @default.
- W2011292013 title "Spectral and physico-chemical investigations of novel homo-dinuclear di-μ2-alkoxo bridged Schiff base complexes: 57Fe Mössbauer parameters of the Fe(III) complex" @default.
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- W2011292013 doi "https://doi.org/10.1016/j.saa.2009.12.010" @default.
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