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- W2011295093 abstract "Composites consisting of multi-walled carbon nanotubes (MWCNTs) and iron–nitrogen containing compounds as catalysts for the electroreduction of oxygen in acidic media were directly prepared on a glassy carbon (GC) electrode in a bottom-up synthesis. In a first step, MWCNTs were drop-coated in form of an ink onto the electrode. Afterwards the nanotubes were modified with catalytically active films of iron porphyrin (FeTMPP-Cl) or iron phenanthroline (Fe(phen)3) through a pulsed potential deposition technique. Finally the prepared electrodes were heat-treated in an inert gas atmosphere. By employing cyclic voltammetry and rotating disc electrode measurements it is shown that the activity for the oxygen reduction reaction (ORR) at such composites increases progressively with every applied synthesis step showing the possibility for direct synthesis of a catalyst on an electrode. The activities of FeTMPP-Cl/MWCNT and Fe(phen)3/MWCNT composites prepared by this technique are higher than that of similar electrocatalysts prepared by wet impregnation and heat treatment. The presented approach opens possibilities for systematic tuning of electrode structures, for example by stepwise build-up of gas diffusion electrodes." @default.
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- W2011295093 date "2010-11-01" @default.
- W2011295093 modified "2023-10-07" @default.
- W2011295093 title "Carbon nanotubes modified with electrodeposited metal porphyrins and phenanthrolines for electrocatalytic applications" @default.
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- W2011295093 doi "https://doi.org/10.1016/j.electacta.2009.11.092" @default.
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