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- W2011297730 abstract "A new mechanism to cause for ferromagnetism of C60 complexes with tetrakis(dimethylamino)ethylene (TDAE) is proposed. This mechanism is based on charge-transfer induced intramolecular Jahn-Teller (CTJT) distortion and intermolecular cooperative Jahn-Teller (CJT) distortion, and ferromagnetism is caused by orbital ordering. The magnitude of CTJT distortion has been estimated by semi-empirical molecular orbital (MO) calculations for a single C60 anion. The CJT distortion and ferromagnetism have been investigated with use of exact diagonalization procedure for one-dimensional multi-band Hubbard Hamiltonian. Finally we propose possible JT-distorted crystal structures which are likely to exhibit three-dimensional ferromagnetic ordering. We also suggest certain measurements which may confirm the proposed model." @default.
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- W2011297730 date "1997-01-01" @default.
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- W2011297730 title "A theoretical model for ferromagnetism of TDAE-C60" @default.
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