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- W2011343861 abstract "Isomerization of n-pentane to iso-pentane was studied on a series of ZSM-5 zeolite catalysts under H 2 and N 2 atmosphere. H-ZSM-5 catalyst showed low n-pentane conversion and iso-pentane selectivity. Pt-ZSM-5 catalyst prepared using ion exchange method showed high activity and high iso-pentane selectivity reaching an equilibrium conversion. A hybrid catalyst prepared by physically mixing H-ZSM-5 and Pt/SiO 2 catalyst showed high activity and selectivity equal to those of Pt/ZSM-5 while Pt/SiO 2 and H-ZSM-5 have poor catalytic performance for this reaction. The hybrid catalyst containing Pd showed high activity and selectivity but Pd ion exchanged ZSM-5 catalyst did not. On the hybrid catalyzed reaction, the mixing state of H-ZSM-5 and Pt/SiO 2 had strong effect on the activity and iso-pentane selectivity. Also in the absence of H 2 , conversion of n-pentane was reduced dramatically and origomerization reaction became dominant. These results suggest that spilled-over hydrogen has important role in paraffin activation and stabilization of intermediates." @default.
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- W2011343861 date "1993-01-01" @default.
- W2011343861 modified "2023-10-02" @default.
- W2011343861 title "Hydroisomerization of n-pentane over hybrid catalysts containing supported hydrogenation catalyst" @default.
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- W2011343861 doi "https://doi.org/10.1016/s0167-2991(08)63169-9" @default.
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