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- W2011343923 abstract "An absolute kinetic study of the reaction of Cl atoms with CF3CF2CH2OH is reported as a function of temperature (T = 268–377 K) and at a total pressure of 100 Torr by the Pulsed Laser Photolysis - Resonance Fluorescence (PLP-RF) technique. No pressure dependence of the rate coefficient for the title reaction, k, was observed between 50 and 200 Torr of He at 298 K. The derived Arrhenius expression in that T-range was k(T) = (2.18 ± 0.24) × 10−12 exp(–(333 ± 34)/T) cm3 molecule−1 s−1, where the uncertainties are ±2σ. From these results, the average tropospheric lifetime of CF3CF2CH2OH due to the reaction with Cl was estimated to be 50 years, considering a global Cl concentration of 103 atom cm−3 and an average temperature of 272 K. Additionally, a theoretical study of the Cl + CF3CF2CH2OH reaction has been carried out by ab initio Moller–Plesset second-order perturbation treatment with 6-311G** basis set to investigate the reaction mechanism. Molecular energies of the different critical points of the potent..." @default.
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- W2011343923 date "2012-11-28" @default.
- W2011343923 modified "2023-10-08" @default.
- W2011343923 title "An experimental and theoretical study on the reaction of Cl with CF3CF2CH2OH" @default.
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- W2011343923 doi "https://doi.org/10.1080/00268976.2012.745627" @default.
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