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- W2011373301 abstract "Zusammenfassung Reaction of [M(CO) 3 ] 2 -μ-[(η 5 -Cp) 2 SiMe 2 ] (M = Mo, W) with Me 2 P-PMe 2 in boiling toluene produces the oxidative coupling products with two bridging PMe 2 ligands. In the case of M = W a second compound, with a mixed hydrido and dimethylphosphido bridge, can be isolated. Thermolysis of the bis-phosphido bridged complexes affords new species of the general formula [M 2 (CO) 3 (PMe 2 ) 2 ]-μ-](η 5 -Cp) 2 SiMe 2 ]. The 31 P NMR spectra indicate two equivalent P nuclei. A large 183 W 31 P spin-spin coupling constant of J (WP) 389.4 Hz points to a partial tungsten-phosphorus double bond. In relation to the diastereomerism of the Me groups of each phosphorus atom of the PMP-unit (M = Mo, W), a heteroallylic ligand which is bound to the second metal centre as a four π-electron donor, is suggested." @default.
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- W2011373301 date "1986-09-01" @default.
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- W2011373301 title "Kooperative wirkung in π-ligandverbrückten zweikernkomplexe IV. Reaktivität von [M(CO)3]2-μ-[η5-Cp)2SiMe2] gegenüber tetramethyldiphosphan:bildung eines neuartigen PMP-heteroallylsystems (M = Mo, W)" @default.
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- W2011373301 doi "https://doi.org/10.1016/0022-328x(86)80240-6" @default.
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