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- W2011388767 abstract "Abstract The reaction of (1 R ,2 S ,3 R )- exo -3[( R )-2-phenyl-2-hydroxyethyl]sulphenyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-ol ( 1 ) with Cp ∗ TiCl 3 in the presence of Et 3 N furnishes the product Cp ∗ Ti(OC 18 H 24 SO)Cl in high yield {Cp ∗ = pentamethylcyclopentadienyl; OC 18 } H 24 SO = (1 R ,2 S ,3 R )- exo -3[(R)-2- phenyl -2-olato-ethyl]sulphyl-1,7,7-trimethylbicyclo [2.2.1]heptan-2-olato. The structure of Cp ∗ Ti(OC 18 H 24 SO)Cl·C 6 H 6 ( 2 ) has been determined by X-ray crystallography. The reaction of Cp 2 Ti(X)Cl (X = Me, Cl) with 2-methoxybenzyl alcohol in the presence of Et 3 N under refluxing benzene gave the product Cp 2 Ti(X)( o -OCH 2 C 6 H 4 OMe) (X = Cl, Me)." @default.
- W2011388767 created "2016-06-24" @default.
- W2011388767 creator A5016502428 @default.
- W2011388767 date "1995-09-01" @default.
- W2011388767 modified "2023-09-27" @default.
- W2011388767 title "Preparation of some cyclopentadienyl titanium complexes and crystal structure of (η5-pentamethylcyclopentadienyl) {(1R,2S,3R)-exo-3[(R)-2-phenyl-2-olato-ethyl}] sulphenyl-1,7,7-trimethylbicyclo[2.2.1]heptan-2-olato chlorotitanium(IV): [Cp∗Ti(OC18H24SO)Cl]·C6H6" @default.
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- W2011388767 doi "https://doi.org/10.1016/0277-5387(95)00113-7" @default.
- W2011388767 hasPublicationYear "1995" @default.
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