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• W2011402536 abstract "Ru3(CO)12 is a very efficient catalyst for the deoxygeiiation of 2-nitro-N-(phenylmethylene) benzeneamine derivatives to give the corresponding 2-substituted benzinmidazoles, at 220 °C and 50 bar of carbon monoxide. Main byproducts are the corresponding amines. The same benzimidazoles are also obtained starting from o-nitroaniline and the corresponding aldehyde. When N-(2-nitrophenyl)methylene benzeneamine derivatives are used as substrates, the reaction changes dramatically and only traces of the corresponding heterocyclic compounds are obtained, although complete conversion of the starting nitro compounds is achieved." @default.
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• W2011402536 date "1992-03-01" @default.
• W2011402536 modified "2023-09-25" @default.
• W2011402536 title "Ruthenium carbonyl-catalyzed deoxygenation by carbon monoidde of o-substituted nitrobenzenes. Synthesis of benzimidazoles" @default.
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• W2011402536 doi "https://doi.org/10.1016/0304-5102(92)85006-2" @default.
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