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- W2011437776 endingPage "118" @default.
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- W2011437776 abstract "Hydrogen bonding in the phosphine chalcogenide series Ph2P(X)CH2OH (X=O, 1; S, 2; Se, 3) has been investigated by single crystal X-ray crystallography. While the phosphine oxide exhibits a dimer motif, the sulfide and selenide form infinite chains; in all cases hydrogen bonding is from the OH group to the phosphine chalcogenide heteroatom. The trend in the hydrogen bond angle for OH⋯X–P, which is 117, 87 and 84° for the oxide, sulfide and selenide, respectively, is explained with respect to the geometry of electron density on the phosphine chalcogenide heteroatom." @default.
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- W2011437776 date "2002-06-01" @default.
- W2011437776 modified "2023-09-23" @default.
- W2011437776 title "Hydrogen bonding in hydroxymethylphosphine chalcogenides" @default.
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- W2011437776 doi "https://doi.org/10.1016/s0020-1693(02)00811-3" @default.
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