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- W2011444095 abstract "The accidental formation of Zn(II) bis(N,N-diethyldithiocarbamate) (1) and Cd(II) bis(N,N diethyldithiocarbamate) (2) during the synthesis of the target heterobinuclear Mo-Cd-dithiocarbamate or Mo-Zn-dithiocarbamtes were crystallized and the molecular structures were determined. As the dispute over the presence of Mo with Zn-dithiocarbamate existed, single crystal EPR measurement was performed. Interestingly the doublet EPR signals of 63Cu and 65Cu patterns were observed. Single crystals of Zn2(Et2dtc)4 containing approximately 2% of Cu2+ in the host lattice showed the doublet spectral characteristic of the Cu2+ ions (S = 1/2, I = 3/2). Both the molecular structures 1 and 2 were identical dimers. The cell parameters of the crystals were refined with low residual factor compared to those of the reported structures. (© 2006 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)" @default.
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- W2011444095 date "2006-12-01" @default.
- W2011444095 modified "2023-09-25" @default.
- W2011444095 title "Refinement, comparisonal study and EPR measurements on the molecular structure of NN-diethyldithiocarbamate of Zn(II) and Cd(II)" @default.
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- W2011444095 doi "https://doi.org/10.1002/crat.200610758" @default.
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