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- W2011445812 abstract "The authors report $^{13}mathrm{C}$ NMR studies of $^{13}mathrm{C}$O adsorbed on small Pt particles and show that the data yield quantitative information about the CO-Pt bond. They find that the $^{13}mathrm{C}$ resonance position is shifted 200 ppm to higher frequency than in CO gas. They prove that the shift arises from polarization of the electron spins in the bond (a Knight shift) by showing that the spin-lattice relaxation obeys the Korringa law. Using ESR results from CO radicals, they deduce the local density of states of the CO $5ensuremath{sigma}$ orbital on the carbon atom at the Fermi energy. The NMR also reveals diffusion of CO on the Pt surface." @default.
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- W2011445812 date "1985-01-07" @default.
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- W2011445812 title "NMR Study of the Chemisorption Bond of Carbon Monoxide on Platinum" @default.
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- W2011445812 doi "https://doi.org/10.1103/physrevlett.54.71" @default.
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