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- W2011489711 abstract "The laser photolysis of sym-triazine optically excited at 265 nm was studied in acetonitrile, cyclohexane and isopropyl alcohol. The TT absorption spectrum was observed with maxima at 245 and 303 nm and shoulders at ≈ 345 and ≈ 450 nm. It decays with a rate k = (1.1 ± 0.1) × 106 s−1 in acetonitrile solution. The triplet is assigned as (n, π*) in character based on the efficient quenching by H-atom donors, e.g., cyclohexane and isopropyl alcohol (kq ≈ (1 − 2) × 108 M−1 s−1). The formation of the azyl radical and the corresponding solvent radicals from these reactions have been observed and identified." @default.
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- W2011489711 title "Formation and reactions of the triplet state of sym-triazine in solution studied by laser spectroscopy" @default.
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