Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011499613> ?p ?o ?g. }
- W2011499613 endingPage "289" @default.
- W2011499613 startingPage "281" @default.
- W2011499613 abstract "The steam reforming of 1:2 phenol–ethanol mixture (ca. 80 gph + eth/N m3 in He) as a model of biomass gasification tar, has been investigated over Ni/Al2O3, Ni/MgO-Al2O3 and Ni/ZnO-Al2O3 catalysts. In this paper interest is focused over a 5% Ni-Al2O3 catalyst, that has been characterized in the unreduced and reduced states by IR of CO adsorbed at low temperature. The steam reforming reaction of ethanol and phenol has also been studied, separately, by IR spectroscopy. In spite of its low Ni content and the absence of alkali and alkali earth ions, this catalyst is actually active in the steam reforming of both ethanol and phenol. The reaction is, however, shifted to higher temperature than with catalysts containing higher Ni-loadings and also Mg and/or Zn ions. Ethanol steam reforming occurs at lower temperature than phenol steam reforming and does not seem to be much hindered by the presence of phenol. Phenol steam reforming in the presence of ethanol starts after, but is highly selective to COx and H2. At low temperature, however, alkylation of phenol mainly occurs over the 5% Ni-Al2O3 catalyst to give mostly o-ethylphenol. Active ethoxide, acetate and phenate species are observed on the surface." @default.
- W2011499613 created "2016-06-24" @default.
- W2011499613 creator A5006978252 @default.
- W2011499613 creator A5020009712 @default.
- W2011499613 creator A5038015430 @default.
- W2011499613 creator A5048431187 @default.
- W2011499613 date "2012-02-01" @default.
- W2011499613 modified "2023-10-01" @default.
- W2011499613 title "Steam reforming of phenol–ethanol mixture over 5% Ni/Al2O3" @default.
- W2011499613 cites W145094960 @default.
- W2011499613 cites W1969508782 @default.
- W2011499613 cites W1974031574 @default.
- W2011499613 cites W1981917819 @default.
- W2011499613 cites W1984060311 @default.
- W2011499613 cites W1985246026 @default.
- W2011499613 cites W1988313769 @default.
- W2011499613 cites W1989184526 @default.
- W2011499613 cites W1992299056 @default.
- W2011499613 cites W2003449412 @default.
- W2011499613 cites W2005238795 @default.
- W2011499613 cites W2010989311 @default.
- W2011499613 cites W2011735785 @default.
- W2011499613 cites W2013384101 @default.
- W2011499613 cites W2014846755 @default.
- W2011499613 cites W2021409051 @default.
- W2011499613 cites W2021463326 @default.
- W2011499613 cites W2021990899 @default.
- W2011499613 cites W2022192501 @default.
- W2011499613 cites W2035591552 @default.
- W2011499613 cites W2036102870 @default.
- W2011499613 cites W2038672340 @default.
- W2011499613 cites W2039687092 @default.
- W2011499613 cites W2042507318 @default.
- W2011499613 cites W2044461886 @default.
- W2011499613 cites W2050306224 @default.
- W2011499613 cites W2059065992 @default.
- W2011499613 cites W2075747430 @default.
- W2011499613 cites W2083468126 @default.
- W2011499613 cites W2086474671 @default.
- W2011499613 cites W2089072035 @default.
- W2011499613 cites W2091656068 @default.
- W2011499613 cites W2094072462 @default.
- W2011499613 cites W2107918810 @default.
- W2011499613 cites W2120446525 @default.
- W2011499613 cites W2144832492 @default.
- W2011499613 cites W2148635767 @default.
- W2011499613 cites W2745496019 @default.
- W2011499613 cites W2951894306 @default.
- W2011499613 doi "https://doi.org/10.1016/j.apcatb.2011.11.048" @default.
- W2011499613 hasPublicationYear "2012" @default.
- W2011499613 type Work @default.
- W2011499613 sameAs 2011499613 @default.
- W2011499613 citedByCount "30" @default.
- W2011499613 countsByYear W20114996132012 @default.
- W2011499613 countsByYear W20114996132013 @default.
- W2011499613 countsByYear W20114996132014 @default.
- W2011499613 countsByYear W20114996132015 @default.
- W2011499613 countsByYear W20114996132016 @default.
- W2011499613 countsByYear W20114996132017 @default.
- W2011499613 countsByYear W20114996132018 @default.
- W2011499613 countsByYear W20114996132019 @default.
- W2011499613 countsByYear W20114996132020 @default.
- W2011499613 countsByYear W20114996132022 @default.
- W2011499613 countsByYear W20114996132023 @default.
- W2011499613 crossrefType "journal-article" @default.
- W2011499613 hasAuthorship W2011499613A5006978252 @default.
- W2011499613 hasAuthorship W2011499613A5020009712 @default.
- W2011499613 hasAuthorship W2011499613A5038015430 @default.
- W2011499613 hasAuthorship W2011499613A5048431187 @default.
- W2011499613 hasConcept C13965031 @default.
- W2011499613 hasConcept C161790260 @default.
- W2011499613 hasConcept C178790620 @default.
- W2011499613 hasConcept C179104552 @default.
- W2011499613 hasConcept C185592680 @default.
- W2011499613 hasConcept C192643346 @default.
- W2011499613 hasConcept C199360897 @default.
- W2011499613 hasConcept C202189072 @default.
- W2011499613 hasConcept C2777702071 @default.
- W2011499613 hasConcept C2779607525 @default.
- W2011499613 hasConcept C2780161600 @default.
- W2011499613 hasConcept C41008148 @default.
- W2011499613 hasConcept C43535742 @default.
- W2011499613 hasConceptScore W2011499613C13965031 @default.
- W2011499613 hasConceptScore W2011499613C161790260 @default.
- W2011499613 hasConceptScore W2011499613C178790620 @default.
- W2011499613 hasConceptScore W2011499613C179104552 @default.
- W2011499613 hasConceptScore W2011499613C185592680 @default.
- W2011499613 hasConceptScore W2011499613C192643346 @default.
- W2011499613 hasConceptScore W2011499613C199360897 @default.
- W2011499613 hasConceptScore W2011499613C202189072 @default.
- W2011499613 hasConceptScore W2011499613C2777702071 @default.
- W2011499613 hasConceptScore W2011499613C2779607525 @default.
- W2011499613 hasConceptScore W2011499613C2780161600 @default.
- W2011499613 hasConceptScore W2011499613C41008148 @default.
- W2011499613 hasConceptScore W2011499613C43535742 @default.
- W2011499613 hasLocation W20114996131 @default.
- W2011499613 hasOpenAccess W2011499613 @default.
- W2011499613 hasPrimaryLocation W20114996131 @default.