Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011531982> ?p ?o ?g. }
Showing items 1 to 89 of
89
with 100 items per page.
- W2011531982 endingPage "1829" @default.
- W2011531982 startingPage "1815" @default.
- W2011531982 abstract "Abstract To draw a relationship between surface concentration of the siloxane segment and adhesion performance, surface properties of the polydimethylsiloxane—poly(methyl methacrylate) block copolymers(PDMS‐ b ‐PMMA) prepared via poly(azo‐containing siloxaneamide)s and their PMMA blends have been studied by measurements of FT‐IR spectra, water contact angle, ESCA spectra and 180° peel strength toward pressure‐sensitive adhesive tape. The water contact angles of the chloroform‐cast blend films increased abruptly with siloxane bulk concentrations, or siloxane contents, particularly, on the air‐side surfaces to reach almost 100° in low siloxane content. A marked increase of the contact angle was observed in the blends containing siloxane chain length (SCL) of longer than 2000. ESCA data evidently confirmed for these blend systems that the siloxane segments with low surface energy were accumulated or enriched mainly on the air‐side surface, and that, on the other hand, polar PMMA segments with high surface energy were oriented to the glass‐side surface and the inside of the films. This surface accumulation behavior of the siloxane segments reflected the 180° peel strength, as a measure of adhesion performance. The water contact angle and 180° peel strength were unequivocally correlated to the siloxane surface concentration estimated from ESCA data. Conversely, in the compression‐molded blend films made by a hydraulic press between a Teflon and a stainless steel plate, the extent of surface accumulation of the PDMS segment was lower than that of the chloroform‐cast films, suggesting lower degree of segment migration in hot‐press films, probably due to substrate surface energy and lower relaxation in the blend melts." @default.
- W2011531982 created "2016-06-24" @default.
- W2011531982 creator A5033913974 @default.
- W2011531982 creator A5052376362 @default.
- W2011531982 creator A5054907336 @default.
- W2011531982 creator A5070681050 @default.
- W2011531982 creator A5079011390 @default.
- W2011531982 date "1990-01-01" @default.
- W2011531982 modified "2023-10-06" @default.
- W2011531982 title "Surface characteristics of polydimethylsiloxane—poly(methyl methacrylate) block copolymers and their PMMA blends" @default.
- W2011531982 cites W1969582098 @default.
- W2011531982 cites W1984314729 @default.
- W2011531982 cites W1994231925 @default.
- W2011531982 cites W2000832026 @default.
- W2011531982 cites W2002069490 @default.
- W2011531982 cites W2010538019 @default.
- W2011531982 cites W2012790658 @default.
- W2011531982 cites W2015228946 @default.
- W2011531982 cites W2037959032 @default.
- W2011531982 cites W2044444599 @default.
- W2011531982 cites W2075832969 @default.
- W2011531982 cites W2079741064 @default.
- W2011531982 cites W2080737003 @default.
- W2011531982 cites W2085760633 @default.
- W2011531982 cites W2105191409 @default.
- W2011531982 cites W2107528373 @default.
- W2011531982 cites W2483066629 @default.
- W2011531982 cites W2495050911 @default.
- W2011531982 cites W4236975746 @default.
- W2011531982 doi "https://doi.org/10.1002/app.1990.070410737" @default.
- W2011531982 hasPublicationYear "1990" @default.
- W2011531982 type Work @default.
- W2011531982 sameAs 2011531982 @default.
- W2011531982 citedByCount "28" @default.
- W2011531982 countsByYear W20115319822012 @default.
- W2011531982 countsByYear W20115319822014 @default.
- W2011531982 countsByYear W20115319822018 @default.
- W2011531982 countsByYear W20115319822020 @default.
- W2011531982 crossrefType "journal-article" @default.
- W2011531982 hasAuthorship W2011531982A5033913974 @default.
- W2011531982 hasAuthorship W2011531982A5052376362 @default.
- W2011531982 hasAuthorship W2011531982A5054907336 @default.
- W2011531982 hasAuthorship W2011531982A5070681050 @default.
- W2011531982 hasAuthorship W2011531982A5079011390 @default.
- W2011531982 hasConcept C15920480 @default.
- W2011531982 hasConcept C159985019 @default.
- W2011531982 hasConcept C188027245 @default.
- W2011531982 hasConcept C192562407 @default.
- W2011531982 hasConcept C195839 @default.
- W2011531982 hasConcept C2776139660 @default.
- W2011531982 hasConcept C2777935641 @default.
- W2011531982 hasConcept C2779849746 @default.
- W2011531982 hasConcept C2780718992 @default.
- W2011531982 hasConcept C521977710 @default.
- W2011531982 hasConcept C6556556 @default.
- W2011531982 hasConcept C84416704 @default.
- W2011531982 hasConceptScore W2011531982C15920480 @default.
- W2011531982 hasConceptScore W2011531982C159985019 @default.
- W2011531982 hasConceptScore W2011531982C188027245 @default.
- W2011531982 hasConceptScore W2011531982C192562407 @default.
- W2011531982 hasConceptScore W2011531982C195839 @default.
- W2011531982 hasConceptScore W2011531982C2776139660 @default.
- W2011531982 hasConceptScore W2011531982C2777935641 @default.
- W2011531982 hasConceptScore W2011531982C2779849746 @default.
- W2011531982 hasConceptScore W2011531982C2780718992 @default.
- W2011531982 hasConceptScore W2011531982C521977710 @default.
- W2011531982 hasConceptScore W2011531982C6556556 @default.
- W2011531982 hasConceptScore W2011531982C84416704 @default.
- W2011531982 hasIssue "7-8" @default.
- W2011531982 hasLocation W20115319821 @default.
- W2011531982 hasOpenAccess W2011531982 @default.
- W2011531982 hasPrimaryLocation W20115319821 @default.
- W2011531982 hasRelatedWork W1978444047 @default.
- W2011531982 hasRelatedWork W1982102224 @default.
- W2011531982 hasRelatedWork W1984314729 @default.
- W2011531982 hasRelatedWork W2008895734 @default.
- W2011531982 hasRelatedWork W2011531982 @default.
- W2011531982 hasRelatedWork W2014366769 @default.
- W2011531982 hasRelatedWork W2022385982 @default.
- W2011531982 hasRelatedWork W2028948581 @default.
- W2011531982 hasRelatedWork W2075463143 @default.
- W2011531982 hasRelatedWork W4297336929 @default.
- W2011531982 hasVolume "41" @default.
- W2011531982 isParatext "false" @default.
- W2011531982 isRetracted "false" @default.
- W2011531982 magId "2011531982" @default.
- W2011531982 workType "article" @default.