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- W2011545160 abstract "New double salts Ag 2 C 2 ·6AgO 2 CCHF 2 ( 1 ), [HPyCH 2 OH][Ag 9 (C 2 )(CF 3 CO 2 ) 9 (HPyCH 2 OH)(H 2 O)]·0.5H 2 O (PyCH 2 OH=4-(hydroxymethyl)pyridine) ( 2 ), Ag 2 C 2 ·5CF 3 SO 3 Ag·2MeCN·2H 2 O ( 3 ) and Ag 2 C 2 ·8CF 3 SO 3 Ag·2EtCN·3H 2 O ( 4 ) have been synthesized by dissolving Ag 2 C 2 in an aqueous solution of the corresponding silver salt followed by the addition of an ancillary ligand. Complex 1 has a three-dimensional structure in which unprecedented basket-like silver cages are inter-connected by difluoroacetate ligands. In 2 , centrosymmetric (C 2 ) 2 @Ag 14 double cages with each half taking the shape of a triangulated dodecahedron are linked through additional silver atoms to generate an infinite chain, and unsupported silver(I)–silver(I) interactions exist between neighboring chains. Of the two independent 4-(hydroxymethyl)pyridinium ions in 2 , one acts in the O -ligating mode, which is observed for the first time, while the other merely serves to provide charge balance and space-filling. Both 3 and 4 are layer-type structures in which the basic building unit is a distorted monocapped octahedron and monocapped trigonal prism, respectively. Ag 2 C 2 ·6AgO 2 CCHF 2 ( 1 ) has a three-dimensional structure containing basket-like silver cages. In [HPyCH 2 OH][Ag 9 (C 2 )(CF 3 CO 2 ) 9 (HPyCH 2 OH)(H 2 O)]·0.5H 2 O (PyCH 2 OH=4-(hydroxymethyl)pyridine) ( 2 ), centrosymmetric (C 2 ) 2 @Ag 14 double cages are linked through additional silver atoms to generate an infinite chain, and one of the two independent 4-(hydroxymethyl)pyridinium ions acts in the O -ligating mode, which is observed for the first time. Both Ag 2 C 2 ·5CF 3 SO 3 Ag·2MeCN·2H 2 O ( 3 ) and Ag 2 C 2 ·8CF 3 SO 3 Ag·2EtCN·3H 2 O ( 4 ) have layer-type structures." @default.
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- W2011545160 date "2003-03-01" @default.
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- W2011545160 title "Structural varieties in double salts of silver acetylide containing ancillary anions and terminal ligands" @default.
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- W2011545160 doi "https://doi.org/10.1016/s0022-328x(03)00013-5" @default.
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