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- W2011562382 abstract "Abstract The cavity formation energy (CFE) is the free energy invested in rearrangement of the solvent molecules when a solute is inserted into a solvent, which is very important to the solubility studies. The CFE of liquid solvents; n -heptane, n -octane, cyclohexane, tetrachloromethane, benzene and water at 298.15 K has been determined. The solubility (in terms of Henry’s law constant), Gibb’s free energy of solution and Δ G s * , the thermodynamical quantities for the solvation process defined by Ben-Naim and Marcus of fluorine containing gases; freon-11, freon-12, freon-13, freon-14, freon-21, freon-c-318 and sulpherhexafluoride (SF 6 ) in above liquid solvents at 298.15 K also been calculated with this cavity formation energy. It yields good agreement with experimental results. The calculation shows importance of CFE in determining the solution properties." @default.
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- W2011562382 date "2004-05-01" @default.
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- W2011562382 title "Solubility of freons in polar and non-polar liquids at 298.15 K" @default.
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- W2011562382 doi "https://doi.org/10.1016/j.jfluchem.2003.09.005" @default.
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