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- W2011569454 abstract "A simple theory is presented for the electron affinity of a small cluster of polar molecules (${mathrm{NH}}_{3}$${)}_{mathrm{n}}$. We obtain that the excess electron is bound inside the cluster essentially by the electric field resulting from the polarization of the molecular dipole moments. In agreement with experiment we obtain a sharp transition from unstable (${mathrm{NH}}_{3}$${)}_{mathrm{n}}$${mathrm{}}^{mathrm{ensuremath{-}}}$ to stable (${mathrm{NH}}_{3}$${)}_{mathrm{n}+1}$${mathrm{}}^{mathrm{ensuremath{-}}}$ with a large barrier against dissociation for a critical cluster size n of about 30." @default.
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- W2011569454 date "1987-06-22" @default.
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- W2011569454 title "Theory for the electron affinity of small clusters of polar molecules (<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>NH</mml:mi></mml:mrow><mml:mrow><mml:mn>3</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math><mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mo>)</mml:mo></mml:mrow><mml:mrow><mml:mi mathvariant=normal>n</mml:mi></mml:mrow></mml:…" @default.
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- W2011569454 doi "https://doi.org/10.1103/physrevlett.58.2635" @default.
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