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- W2011578251 abstract "The kinetics of decarboxylation of the α-substituted acrylic acid itaconic acid were analyzed at 280−330 °C, 275 bar, and solution pH25 = 0.8−5.75 using an FTIR spectroscopy flow reactor. As the pH was increased, the observed rate constant initially decreased to a minimum at pH25 = 1.82, then increased and reached its maximum at pH25 = 3.75, and then decreased again up to the limit of study at pH25 = 5.75. The decarboxylation rate depends on the molecular form of itaconic acid in the order of itaconate monoanion > protonated itaconic acid > neutral itaconic acid ≈ itaconate dianion. Insight into possible reasons for this trend was obtained from geometry-optimized structures using density functional theory with the B3LYP method at the 6-31+G* level." @default.
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- W2011578251 date "2001-11-02" @default.
- W2011578251 modified "2023-09-27" @default.
- W2011578251 title "Spectroscopy of Hydrothermal Solutions 18: pH-Dependent Kinetics of Itaconic Acid Reactions in Real Time" @default.
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- W2011578251 doi "https://doi.org/10.1021/jp012501s" @default.
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