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• W2011579760 startingPage "2527" @default.
• W2011579760 abstract "The (E)- and (Z)-styryl isomers of trans-[Pd(CH═CHPh)Br(PMePh2)2] (1a) and [Pd(η2-PhCH═CHPMePh2)Br(PMePh2)] (2a) were prepared, and their C−P reductive elimination (1a → 2a) and C−P oxidative addition (2a → 1a) behaviors examined. Kinetics and thermodynamics of the reactions are strongly affected by E/Z configurations of the styryl group and solvent polarity. Complex (E)-1a readily undergoes C−P reductive elimination in CD2Cl2 as a polar solvent in high selectivity. On the other hand, while the (Z)-isomer of 1a is unreactive toward reductive elimination, (Z)-2a undergoes C−P oxidative addition favorably in nonpolar benzene. X-ray diffraction analysis and DFT calculations for 1a and 2a provided reasonable accounts for these reaction features. Kinetic examinations revealed two types of C−P reductive elimination processes, which involve predissociation and association of the PMePh2 ligand, respectively." @default.
• W2011579760 created "2016-06-24" @default.
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• W2011579760 creator A5040122242 @default.
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• W2011579760 date "2009-03-23" @default.
• W2011579760 modified "2023-09-23" @default.
• W2011579760 title "Mechanism of C−P Reductive Elimination from <i>trans</i>-[Pd(CH═CHPh)Br(PMePh₂)₂]" @default.
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• W2011579760 doi "https://doi.org/10.1021/om801207k" @default.
• W2011579760 hasPublicationYear "2009" @default.
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