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• W2011587710 abstract "The structure of the isoprene (2-methyl-buta-1,3-diene) molecule has been studied by vibrational spectroscopy and gas electron diffraction techniques. A normal coordinate analysis was used to calculate the vibrational frequencies for the anti (s-trans), gauche and syn (s-cis) conformers of the molecule. Assignments of some frequencies of the anti form were revised. The experimental bands at 1255, 635, 555, 419 and 311 cm−1 are assigned as fundamentals of the gauche conformer with a high degree of confidence. Among the structural parameters determined by electron diffraction are the following bond distances (in Å): CC 1.340, CC 1.463, CCmethyl 1.512, CH 1.076 and CmethylH 1.110. The abundance of the anti form was determined to be 95.3%, while the rest (4.7%) was interpreted as the gauche form with a dihedral angle of 73.5°." @default.
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• W2011587710 date "1984-04-01" @default.
• W2011587710 modified "2023-10-11" @default.
• W2011587710 title "Structure and conformations of isoprene by vibrational spectroscopy and gas electron diffraction" @default.
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• W2011587710 doi "https://doi.org/10.1016/0022-2860(84)80190-8" @default.
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