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• W2011610097 abstract "A second-generation synthesis of the pentacyclic core of the cortistatins, a family of rearranged steroidal alkaloids that have recently attracted much attention, is reported. The improved sequence provides access to significant quantities of this key compound, which enabled a formal total synthesis of (±)-cortistatin A by conversion to the key Nicolaou/Hirama dienone. It is anticipated that this new, robust route to the pentacyclic core will facilitate the total synthesis of a range of natural products in the cortistatin family, as well as the construction of key structural analogs to probe the promising biological activity of these important compounds." @default.
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• W2011610097 date "2010-06-01" @default.
• W2011610097 modified "2023-10-06" @default.
• W2011610097 title "Formal total synthesis of (±)-cortistatin A" @default.
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• W2011610097 doi "https://doi.org/10.1016/j.tet.2010.01.030" @default.
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