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- W2011617926 abstract "Abstract The enantioselective hydrolysis of 3-alkyl- and 3-arylglutaronitriles catalyzed by Rhodococcus sp. AJ270 cells, afforded the corresponding ( S )-3-substituted 4-cyanobutanoic acids with low to moderate enantiomeric purities. Additives such as acetone were found to significantly enhance the enantioselectivity of the desymmetrization, giving enantiomeric excesses of up to 95%. The synthetic potential of the homochiral product was also demonstrated by the preparation of optically active ( R )- and ( S )-4-amino-3-phenylbutanoic acids." @default.
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- W2011617926 date "2002-01-01" @default.
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- W2011617926 title "Enzymatic desymmetrization of 3-alkyl- and 3-arylglutaronitriles, a simple and convenient approach to optically active 4-amino-3-phenylbutanoic acids" @default.
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- W2011617926 doi "https://doi.org/10.1016/s0957-4166(02)00028-9" @default.
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