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• W2011621595 abstract "Several rhodium(I) complexes of the type [RhX(CO)(PePy2)], [Rh(diene)(PePy)]+, and [Rh(diene)(PePy2)]+ (PePyn = P(CH2CH2Py)nPh3-n; Py = 2-pyridyl; n = 1, 2) have been prepared. The two former are square planar; the latter are pentacoordinated for diene = tetrafluorobenzobarrelene or norbornadiene (confirmed by X-ray diffraction), but an equilibrium of 4- and 5-coordinate isomers exists in solution for diene = 1,5-cyclooctadiene. The fluxional behavior of all these complexes is studied by NMR spectroscopy. The complex [Rh(NBD)(PePy2)]PF6.Cl2CH2 crystallizes in the monoclinic space group P21/n with a = 8.455(1) A, b = 18.068(3) A, c = 19.729(3) A, beta = 99.658(3)degrees, and Z = 4. The complexes [Rh(diene)(PePy2)]+ react with CO to give the dimeric complex [Rh2(CO)2[P(CH2CH2Py)2Ph]2](BF4)2 with the pyridylphosphine acting as P,N-chelating and P,N-bridging." @default.
• W2011621595 created "2016-06-24" @default.
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• W2011621595 date "2000-01-27" @default.
• W2011621595 modified "2023-10-10" @default.
• W2011621595 title "Rhodium Complexes with the Chelating and Binucleating Ligands P(CH₂CH₂Py)<i>_n</i>Ph₃_-<i>_n</i> (Py = 2-Pyridyl; <i>n</i> = 1, 2): Structures and Fluxional Behavior" @default.
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• W2011621595 doi "https://doi.org/10.1021/ic990634a" @default.
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