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• W2011657611 abstract "We used a dynamic method to measure the adsorption isotherms for the gases ethane, propane, and n -butane on polystyrene at 273, 298, and 303 K. Concentrations were in the range from 500 to 10,000 ppm in a helium carrier. The isotherms can be represented by either Freundlich or Chakravarti-Dhar types. The exponent in the Freundlich isotherm increases with temperature for all three gases. The coefficient in the Freundlich isotherm increases with temperature for propane and n -butane, but decreases with increasing temperature for ethane. The isosteric heats of adsorption show a strong dependence on surface coverage. The isosteric heats were extracted in three ways: (1) from the calculated isosteres, (2) from the adsorption capacities, and (3) from the adsorption potential. The first two methods agree at all measured concentrations. Values derived from the adsorption potentials at 298 K show more variation. The characteristic curves at the three temperatures are superimposable as a single curve for each gas, but polystyrene does not show a single characteristic curve for all three gases." @default.
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• W2011657611 date "1985-08-01" @default.
• W2011657611 modified "2023-09-25" @default.
• W2011657611 title "Adsorption isotherms and isosteric heats of adsorption for ethane, propane, and n-butane on polystyrene" @default.
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• W2011657611 doi "https://doi.org/10.1016/s0021-9797(85)80014-x" @default.
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