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W2011661707 abstract "Abstract The phase relationships of the quaternary systems MCr2Se4MGa2Se4 (M = Mn, Fe, Co, Ni) and MV2S4MGa2S4 (M = Fe, Ni) and the ternary system NiSGa2S3 were studied by X-ray phase analyses with the aim to prepare new layered structure and spinel-type chalcides. The hitherto unknown selenides MnCr0.5Ga1.5Se4, FeCr0.5Ga1.5Se4, CoCr0.5Ga1.5Se4, and (Ni, Cr, Ga, □)3Se4 (all ZnIn2S4-III type) were obtained and characterized by X-ray and FIR studies. No quaternary chalcides are formed in the systems MV2S4MGa2S4; ternary NiGa2Se4 and CoGa2Se4 were likewise not obtained. Whereas the phase widths of the end-member phases are small (with the exception of α′-Ga2S3 at 1000°C) because of the strong tetrahedral and octahedral site preferences of gallium and both chromium and vanadium, respectively, the quaternary selenides form solid solutions of the type MCr2−2xGa2xSe4 with x = 0.65-0.80 for M = Mn and Fe." @default.
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W2011661707 date "1987-08-01" @default.
W2011661707 modified "2023-09-23" @default.
W2011661707 title "Phase relationships of the quaternary systems MCr2Se4MGa2Se4 (M = Mn, Fe, Co, Ni): New layered ZnIn2S4-III type selenides" @default.
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W2011661707 doi "https://doi.org/10.1016/0022-4596(87)90076-4" @default.
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