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- W2011664098 abstract "(2-Furyl)diphenylphosphane (1), bis(2-furyl)phenylphosphane (8) and tris(2-furyl)phosphane (9) have been converted into their water soluble 5-carboxylates 4, 11 and 12, 5-phosphonates 14 and 16 and 5-sulfinates 17−19. In most cases, the selected route involved a 5-bromo to 5-lithio exchange reaction, followed by reaction with CO2, ClP(O)(OEt)2 or SO2. The furan group sharply enhances the water-solubility of these products when compared with the corresponding benzene derivatives. Catalytic tests in hydrogenation, hydroformylation and Heck cross-coupling reactions showed that the sulfinate group tends to inhibit the catalysis and, in addition, a sharp drop in activity was observed with the trifunctional products 12 and 19. Overall, the phosphonates 14 and 16 appear to be the most promising ligands for biphasic catalysis." @default.
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- W2011664098 date "2000-07-01" @default.
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- W2011664098 title "Water-Soluble Derivatives of Furylphosphanes" @default.
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