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- W2011666148 abstract "The fluorescence of $mathrm{Cd}{mathrm{S}}_{x}{mathrm{Se}}_{1ensuremath{-}x}$ mixed crystals with band-gap gradients as large as 1200 eV/cm has been investigated at 77ifmmode^circelsetextdegreefi{}K. The graded samples were produced by heating CdSe or $mathrm{Cd}{mathrm{S}}_{x}{mathrm{Se}}_{1ensuremath{-}x}$ platelets in a sulfur-selenium atmosphere. Some of the diffused crystals were post-treated in a cadmium atmosphere. Removal of surface material shifted the fluorescence spectra of the diffused crystals to longer wavelengths. The spectral position of fluorescence peaks was determined as a function of the thickness of the removed surface layer. Composition profiles were deduced from these data by correlating fluorescence wavelength with crystal composition. Error-function curves gave a good fit to experimentally determined profiles. Diffusion constants of 7.0 ifmmodetimeselsetexttimesfi{} ${10}^{ensuremath{-}13}$ and 1.6 ifmmodetimeselsetexttimesfi{} ${10}^{ensuremath{-}12}$ ${mathrm{cm}}^{2}$/sec were determined for diffusion temperatures of 600 and 650ifmmode^circelsetextdegreefi{}C, respectively." @default.
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- W2011666148 date "1972-02-15" @default.
- W2011666148 modified "2023-10-17" @default.
- W2011666148 title "Fluorescence of Graded-Band-GapCdSxSe1−xCrystals Produced by Diffusion" @default.
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- W2011666148 doi "https://doi.org/10.1103/physrevb.5.1467" @default.
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