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- W2011684498 abstract "Vibrational lifetimes of the surface hydroxyl groups of zeolites (Y-type and mordenite) were measured in real time by pump-probe absorption spectroscopy using picosecond IR pulses. The relaxation lifetimes of the OH (ν=1) groups of Y-type zeolites which give the OH stretching bands at 3625 and 3540 cm−1 were 180 ± 12 and 63 ± 14 ps, respectively. The influence of the micro-structure of zeolites on the lifetime is discussed. For the surface OH groups of mordenite, the decay time of the transient hot band absorption at 3457 cm−1 (ν=2←1) was also measured by pumping the fundamental band at 3608 cm−1 to be 154 ± 18 ps, which agreed with 161 ± 18 ps obtained from the bleaching experiment of the fundamental band." @default.
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- W2011684498 date "1993-03-01" @default.
- W2011684498 modified "2023-10-10" @default.
- W2011684498 title "Vibrational lifetimes of surface hydroxyl groups of zeolites by picosecond IR pulses" @default.
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- W2011684498 doi "https://doi.org/10.1016/0009-2614(93)90008-o" @default.
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