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• W2011767939 abstract "Photochemical reduction of several 4-picolyl- and N-methyl-4-picolinium esters was examined using product analysis, laser flash photolysis, and fluorescence quenching. It is demonstrated that the radical (anions) formed in these reactions readily fragment to yield a carboxylic acid and a 4-pyridylmethyl radical intermediate. The high chemical and quantum yields observed for these photoreactions suggests that these esters can be used as photolabile protecting groups." @default.
• W2011767939 created "2016-06-24" @default.
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• W2011767939 date "2004-07-17" @default.
• W2011767939 modified "2023-10-16" @default.
• W2011767939 title "C−O Bond Fragmentation of 4-Picolyl- and <i>N</i>-Methyl-4-picolinium Esters Triggered by Photochemical Electron Transfer" @default.
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• W2011767939 doi "https://doi.org/10.1021/jo049501j" @default.
• W2011767939 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/15307722" @default.
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