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- W2011806053 abstract "Three diphosphates of Mo(VI), A2MoO2P2O7 with A = K, Rb and W(VI), K2WO2P2O7 have been synthesized. These phosphates crystallize in the space group C2/c and are isotypic with the chain-like structure (NH4)2MoO2P2O7. The single crystal X-ray structure determination performed on the tungsten diphosphate K2WO2P2O7 shows that the geometry of its [WP2O9]∞ chains is practically identical to that observed for (NH4)2MoO2P2O7: the nature of the M elements (M = Mo, W) and of the A site cation (K, Rb or NH4) does not influence the interatomic distances. Trois diphosphates de molybdène (VI), A2MoO2P2O7 avec A = K et Rb, et de tungstène (VI), K2WO2P2O7 ont été synthétisés. Ces phosphates qui cristallisent dans le groupe d'espace C2/c sont isotypes de (NH4)2MoO2P2O7, qui présente une structure en chaîne. La détermination structurale sur monocristal de K2WO2P2O7 montre que la géométrie de la chaîne [WP2O9]∞ est pratiquement identique à celle observée dans (NH4)2MoO2P2O7: la nature de l'élément M (M = Mo, W) et du site A (K, Rb ou NH4) n'influence pas les distances interatomiques." @default.
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- W2011806053 date "1997-03-01" @default.
- W2011806053 modified "2023-09-25" @default.
- W2011806053 title "New molybdeno-and tungstodiphosphates with the (NH4)2MoO2P2O7 chain-like structure" @default.
- W2011806053 cites W2060200552 @default.
- W2011806053 doi "https://doi.org/10.1016/s1251-8069(99)80024-4" @default.
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