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- W2011814188 abstract "A mesoionic acyclic C-nucleoside 4, generated readily from δ-gluconolactone in a few synthetic steps, serves as the chiral core to construct a series of functionalized nucleosides bearing 2-aza-7-thiabicycle[2.2.1]heptane or 2-(1H)-pyridone moieties as the aglycon. The key step involves a [3+2] cycloaddition of 4 with several olefinic dipolarophiles followed by hydrogen sulfide elimination with mercury(II) acetate." @default.
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- W2011814188 date "2002-03-01" @default.
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- W2011814188 title "Generation and fate of a novel homochiral mesoionic dipole: synthesis of C-nucleoside analogs" @default.
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