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- W2011818140 abstract "Abstract Main group III metal(III)halides react with trimethylsilyl organylsulfides to give dihalo(organylthio)metallanes. In the solid state diiodo(methylthio)gallane as well as diido(i-propylthio)gallane have shown to be present as dimers, whereas in solution these compounds are trimeric. Reactions between dihalo(organyl)metallanes and trimethyl-silyl organylsulfides result via in case of gallium as metal atom in the formation of halo-(organyl)(organylthio)metallanes, consequently compounds with three different ligands on the metal center. In case of aluminium and indium one has to take into account more complicated reaction pathways, which will be discussed in detail. Structural phenomena of the halo(organyl)(organylthio)metal-lanes in solution will be discussed by means of molecular weight determination- as well as NMR-spectroscopic studies." @default.
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- W2011818140 date "1989-01-01" @default.
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- W2011818140 title "Ring Systems of Aluminium-, Gallium-, and Indium Thiolates - A Comparison" @default.
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- W2011818140 doi "https://doi.org/10.1080/10426508908039697" @default.
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