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- W2011837982 abstract "Kinetic isotope effects have been determined for the E2 reaction of some 2-arylethyltrimethyl-ammonium ions with ethoxide in ethanol at 40°. The nitrogen effect, (k 14 /k 15 − 1)100, decreased with increasing electron-withdrawing ability of the para substituent; i.e. 1.37, 1.33, 1.14, and 0.88 for p-OCH 3 , p-H, p-Cl, and p-CF 3 , respectively. Furthermore, the primary hydrogen–deuterium isotope effects increased for the same substituents, respectively; i.e. k H /k D = 2.64, 3.23, 3.48, and 4.16. A large positive ρ value of 3.66 was found as well as a small secondary α-deuterium effect of 1.02 for p-H. In addition, the nitrogen isotope effect decreased with increasing strength of the abstracting base for the reaction of ethyltrimethylammonium ion; i.e. 1.86 and 1.41 at 60° for reaction with EtO − –EtOH and t-BuO − –t-BuOH, respectively. The results are discussed in terms of recent theoretical treatments of the effect of base, substituents, and nature of the leaving group on the nature of the transition state for an E2 process. The conclusion is reached that any structural change which causes one bond (C—H) to be weakened more at the transition state will have a corresponding effect on the other bond [Formula: see text]" @default.
- W2011837982 created "2016-06-24" @default.
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- W2011837982 date "1974-03-01" @default.
- W2011837982 modified "2023-10-12" @default.
- W2011837982 title "Isotope Effect Studies on Elimination Reactions. IX. The Nature of the Transition State for the E2 Reaction of 2-Arylethylammonium Ions with Ethoxide in Ethanol" @default.
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- W2011837982 doi "https://doi.org/10.1139/v74-118" @default.
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