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• W2011848564 abstract "The synthesis and characterization of two 18-crown-6 functionalized analogues of an extensively studied gadolinium texaphyrin derivative, motexafin gadolinium (1, MGd), are reported. These are the monomeric and dimeric species, compounds 2 and 3, respectively. Both crown ether functionalized species proved to be stable at physiological pH and revealed distinct shifts in the UV spectrum when treated with sodium-, potassium-, ammonium- or zinc(II)-salts. Zinc(II) is believed to play a major role regulating apoptosis mechanisms in cancerous cells. Therefore, cytotoxicity studies of 2 and 3 were carried out using the Ramos cell line in the presence and absence of zinc(II)." @default.
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• W2011848564 date "2011-07-01" @default.
• W2011848564 modified "2023-09-25" @default.
• W2011848564 title "Crown ether functionalized texaphyrin monomers and dimers" @default.
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• W2011848564 doi "https://doi.org/10.1142/s108842461100315x" @default.
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