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- W2011893710 abstract "Porphyrins with fluorenyl and fluorenone groups at the meso-positions, and their Zn(II) complexes have been synthesized and characterized by 1H NMR, UV–visible and fluorescence studies. Following selective excitation of the pendant arms with UV light, the energy is transferred to the porphyrin core and reemitted as red light. In comparison to tetraphenylporphyrin 5, the luminescence properties are markedly improved. The fluorescence quantum yields of tetrafluorenylporphyrin 1 and tetrafluorenoneporphyrin 2 are 0.22 and 0.25, respectively. To cite this article: C.O. Paul-Roth, G. Simonneaux, C. R. Chimie 9 (2006). Des porphyrines possédant des groupes fluorenyl et fluorenone en positions méso, et leurs complexes de Zn(II) ont été synthétisés et caractérisés par 1H NMR, spectroscopie UV–visible et de fluorescence. Après une excitation sélective des antennes par lumière UV, l'énergie est transférée vers le cœur de la porphyrine et une lumière rouge est émise. En comparaison avec la tétraphénylporphyrine 5, les propriétés de luminescence sont singulièrement améliorées. Le rendement quantique de fluorescence de la tétrafluorénylporphyrine 1 et de la tétrafluorénoneporphyrine 2 sont 0,22 et 0,25, respectivement. Pour citer cet article : C.O. Paul-Roth, G. Simonneaux, C. R. Chimie 9 (2006)." @default.
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- W2011893710 date "2006-10-01" @default.
- W2011893710 modified "2023-10-07" @default.
- W2011893710 title "Porphyrins with fluorenyl and fluorenone pendant arms as red-light-emitting devices" @default.
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- W2011893710 doi "https://doi.org/10.1016/j.crci.2006.04.003" @default.
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