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• W2011903277 abstract "Vapour phase IR spectra of N-methylaniline and its analogue deuterated on the nitrogen atom are presented between 30 and 425 cm−1. The absorptions associated with the three large amplitude vibrations of this molecule are identified, and potential energy barriers are calculated. The barrier to methyl torsion is found to be 12.9 ± 0.2 kJ mol−1, to HNCH3 torsion 14.5 ± 2.0 kJ mol−1, and to inversion at nitrogen approximately 2 kJ mol−1. These results are consistent with an earlier microwave study [1] but the error limits have been greatly improved. The most surprising result is the confirmation that N-methylaniline is more planar than aniline itself. The barriers to torsion around the NC (ring) bond are compared to those in similar molecules." @default.
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• W2011903277 date "1983-03-01" @default.
• W2011903277 modified "2023-09-27" @default.
• W2011903277 title "The vapour-phase infrared spectrum and large-amplitude vibrations of N-methylaniline" @default.
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• W2011903277 doi "https://doi.org/10.1016/0022-2860(83)90006-6" @default.
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