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- W2011970621 abstract "In this article, we synthesized a series of triphenylene discotic liquid crystals (TPDLCs) containing up to three fluorinated ester chains: C18H6(OCnH2n+1)6−m(O2CC2H4C6F13)m (n = 4–9, 11; m = 1–3); as well as their corresponding non-fluorinated TPDLCs: C18H6(OCnH2n+1)5(O2CC8H17) (n = 4–9, 11), 2,7-C18H6(OC5H11)4(O2CC8H17)2, and C18H6(OC9H19)3(O2CC8H17)3. The compounds were characterized by using nuclear magnetic resonance (NMR), elemental analysis, and mass. Thermal gravimetry analysis (TGA) showed that the FTPDLCs were thermally stable until 300°C. Differential scanning calorimerty (DSC) and polarized optical microscopy (POM) investigations of the mesomorphism found that the FTPDLCs exhibited enantiotropic hexagonal columnar mesophase (Colh) and had much higher clear points than the corresponding hexaalkoxytriphenylenes, C18H6(OR)6. Noticeably, semi-quantitative studies showed that the number of fluorinated ester chains on the triphenylene core was directly proportional to FTPDLCs' clearing points and th..." @default.
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- W2011970621 date "2011-05-31" @default.
- W2011970621 modified "2023-09-22" @default.
- W2011970621 title "Synthesis and Mesomorphism of Triphenylene Discotic Liquid Crystals Containing Fluorinated Chains" @default.
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- W2011970621 doi "https://doi.org/10.1080/1539445x.2010.525444" @default.
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