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- W2011978013 abstract "The photochemical cycloaddition reactions of five- and six-membered α,β-unsaturated lactone derivatives with unsaturated substrates (ethylene, acetylene, 1,1-dimethoxyethylene etc.) have been studied. The parent α,β-unsaturated lactone (γ-crotonolactone) and the β-,γ-, or δ-alkyl substituted derivatives add to ethylene and acetylene in the acetone solutions and to 1,1-dimethoxyethylene in the benzene solutions in so good yields as to utilize them practically for synthesis. α-Phenyl-γ-crotonolactone and β-phenyl-γ-crotonolactone also add to ethylene and acetylene, whereas, α-methyl, β-hydroxy, and β-methoxy derivatives do not. As the synthetic applications of the reactions, the synthesis of (±)-grandisol has been achieved, and the synthetic approach to (±)-canadensolide has also been described." @default.
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- W2011978013 date "1976-02-01" @default.
- W2011978013 modified "2023-10-09" @default.
- W2011978013 title "Photochemical Cycloaddition Reactions of α,β-Unsaturated Lactones with Olefins, and Application to Synthesis of Natural Products" @default.
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- W2011978013 doi "https://doi.org/10.1246/bcsj.49.520" @default.
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