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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2011999548> ?p ?o ?g. }

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• W2011999548 abstract "An interesting cooperation between Candida antarctica Lipase B (CAL-B) and alkaline protease from Bacillus subtilis (BSP) in the copolymerization of bulky ibuprofen-containing hydroxyacid methyl ester (HAEP) and ε-caprolactone (ε-CL) is observed. This cooperation improved the M¯n of the polymers from 3130 (CAL-B) to 9200 g mol-1 (CAL-B/BSP). Experimental results clearly indicate that CAL-B mainly catalyzes the ring-opening polymerization (ROP) of ε-CL under the initiation of HAEP to form the homopolymer of ε-CL, while BSP catalyzes the subsequent polycondensation of the ROP product to yield the copolymer with increased molecular weight. Furthermore, using suitable chemo-enzymatic methods, valuable polyesters with chiral (R)- or (S)-ibuprofen pendants can be tailor-made." @default.
• W2011999548 created "2016-06-24" @default.
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• W2011999548 date "2014-09-08" @default.
• W2011999548 modified "2023-10-10" @default.
• W2011999548 title "Two Enzyme Cooperatively Catalyzed Tandem Polymerization for the Synthesis of Polyester Containing Chiral (<i>R</i>)- or (<i>S</i>)-Ibuprofen Pendants" @default.
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• W2011999548 doi "https://doi.org/10.1002/marc.201400394" @default.
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